En 2014, 
Chapecoense goleó 5–0 a 
Internacional por Campeonato Brasileiro Série A.
Partidos de Livorno
Livorno
L
Final
Atalanta BC
4–2
Atalanta BC
Torino
T
Final
L
Livorno
0–0
Livorno
L
Final
Sampdoria
1–0
Sampdoria
Lazio
Final
L
Livorno
1–0
Livorno
L
Final
P
Palermo
1–2
Chievo
C
Final
L
Livorno
2–1
Livorno
L
Final
R
Reggina
1–1
Parma
P
Final
L
Livorno
1–0
Livorno
L
Final
C
Catania
4–1
Udinese
U
Final
L
Livorno
4–0
Empoli
E
Final
L
Livorno
2–2
Livorno
L
Final
Inter Milan
1–2
Inter Milan
Siena
S
Final
L
Livorno
0–0
Livorno
L
Final
A
Ascoli
0–0
Livorno
L
Final
M
Messina
2–1
AC Milan
Final
L
Livorno
2–1
Livorno
L
Final
C
Cagliari
2–1
ACF Fiorentina
Final
L
Livorno
2–1
Livorno
L
Final
AS Roma
1–1
AS Roma
Atalanta BC
Final
L
Livorno
5–1
Livorno
L
Final
T
Torino
1–1
Sampdoria
Final
L
Livorno
4–1
Livorno
L
Final
Lazio
1–1
Lazio
Palermo
P
Final
L
Livorno
3–0
Livorno
L
Final
C
Chievo
0–2
Reggina
R
Final
L
Livorno
2–2
Livorno
L
Final
P
Parma
3–0
Catania
C
Final
L
Livorno
3–2
Livorno
L
Final
U
Udinese
1–0
Livorno
L
Final
E
Empoli
0–0
Inter Milan
Final
L
Livorno
4–1
Livorno
L
Final
S
Siena
0–0
Ascoli
A
Final
L
Livorno
0–2
Messina
M
Final
L
Livorno
0–1
Livorno
L
Final
AC Milan
0–0
AC Milan
Cagliari
C
Final
L
Livorno
2–2
Livorno
L
Final
ACF Fiorentina
1–0
ACF Fiorentina
AS Roma
Final
L
Livorno
2–0
Livorno
L
Final
Atalanta BC
0–2
Atalanta BC
Livorno
L
Final
B
Bari
1–0
AC Milan
Final
L
Livorno
2–0
Livorno
L
Final
Sampdoria
1–0
Sampdoria
Triestina
T
Final
L
Livorno
5–4
Novara
N
Final
L
Livorno
3–1
Livorno
L
Final
Juventus
1–3
Juventus
Lazio
Final
L
Livorno
2–0
Livorno
L
Final
Inter Milan
0–2
Inter Milan
Padova
P
Final
L
Livorno
2–1
Livorno
L
Final
AS Roma
2–1
AS Roma
Lucchese
L
Final
L
Livorno
0–1
Livorno
L
Final
ACF Fiorentina
1–1
ACF Fiorentina
Livorno
L
Final
PP
Pro Patria
2–0
Bologna
Final
L
Livorno
6–2
Torino
T
Final
L
Livorno
1–0
Livorno
L
Final
P
Palermo
0–2
Genoa CFC
Final
L
Livorno
3–2
Livorno
L
Final
M
Modena
1–0
Atalanta BC
Final
L
Livorno
4–2
Bari
B
Final
L
Livorno
3–0
Livorno
L
Final
AC Milan
2–1
AC Milan
Sampdoria
Final
L
Livorno
3–0
Livorno
L
Final
T
Triestina
1–0
Livorno
L
Final
N
Novara
1–0
Juventus
Final
L
Livorno
2–2
Livorno
L
Final
Lazio
1–1
Lazio
Inter Milan
Final
L
Livorno
3–1
Livorno
L
Final
P
Padova
2–2
AS Roma
Final
L
Livorno
4–0
Livorno
L
Final
L
Lucchese
0–0
ACF Fiorentina
Final
L
Livorno
3–2
Pro Patria
PP
Final
L
Livorno
1–0
Livorno
L
Final
Bologna
1–1
Bologna
Livorno
L
Final
T
Torino
0–2
Palermo
P
Final
L
Livorno
4–2
Livorno
L
Final
Genoa CFC
2–2
Genoa CFC
Modena
M
Final
L
Livorno
0–0
Lucchese
L
Final
L
Livorno
2–2
Bari
B
Final
L
Livorno
3–0
Livorno
L
Final
Atalanta BC
2–0
Atalanta BC
Livorno
L
Final
Sampdoria
1–1
Sampdoria
Torino
T
Final
L
Livorno
5–2
Livorno
L
Final
S
Salernitana
3–0
SSC Napoli
Final
L
Livorno
3–0
Livorno
L
Final
Genoa CFC
1–1
Genoa CFC
Lazio
Final
L
Livorno
4–1
Livorno
L
Final
Bologna
2–0
Bologna
Livorno
L
Final
Juventus
0–0
Juventus
Inter Milan
Final
L
Livorno
1–0
Livorno
L
Final
ACF Fiorentina
2–2
ACF Fiorentina
Pro Patria
PP
Final
L
Livorno
2–0
Livorno
L
Final
A
Alessandria
1–0
AC Milan
Final
L
Livorno
2–0
Livorno
L
Final
M
Modena
1–1
Triestina
T
Final
L
Livorno
1–1
Livorno
L
Final
AS Roma
2–1
AS Roma
Vicenza
V
Final
L
Livorno
1–0
Livorno
L
Final
L
Lucchese
2–0
Livorno
L
Final
B
Bari
1–1
Atalanta BC
Final
L
Livorno
3–1
Sampdoria
Final
L
Livorno
1–1
En 2023, 
J.J. de Urquiza goleó 4–0 a 
San Martín de Burzaco en Fecha 38 de Primera C.
En 2023, 
Deportivo Español goleó 4–0 a 
Puerto Nuevo en Fecha 38 de Primera C.
En 2022, 
Alianza FC goleó 4–0 a 
Independiente Santa Fe en Fecha 16 de Categoría Primera A.
En 2009, 
Serbia goleó 5–0 a 
Romania en Grupo 7 de Eliminatorias UEFA.